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Beilstein J. Org. Chem. 2009, 5, No. 63, doi:10.3762/bjoc.5.63
Graphical Abstract
Scheme 1: Comparison of mesomorphic properties of 1a and 2a.
Scheme 2: Variation of spacer lengths and terminal group at 5-phenylpyrimidine.
Scheme 3: Synthesis of compounds 3–5, 9 and 11.
Scheme 4: Synthesis of compounds 6 and 7.
Figure 1: DSC curve of compound 3d (heating/cooling rate 10 K/min).
Figure 2: Fan-shaped texture of 3e under crossed polarizers upon cooling from the isotropic liquid (magnifica...
Figure 3: DSC curve of compound 4e (heating/cooling rate 5 K/min).
Figure 4: Fan-shaped texture of compound 4d at 45 °C upon cooling from the isotropic liquid (cooling rate 1 K...
Figure 5: DSC curve of compound 6c (heating/cooling rate 10 K/min).
Figure 6: Fan-shaped texture of compound 6e at 45 °C upon cooling from the isotropic liquid (cooling rate 10 ...
Figure 7: Comparison of the mesophase range ΔT for the different spacer lengths of compounds 3, 4 and 6: meso...
Figure 8: Comparison of the mesophase range ΔT for the different spacer lengths of compounds 3, 4 and 6: meso...
Figure 9: Proposed model for the layer structure.
Beilstein J. Org. Chem. 2009, 5, No. 57, doi:10.3762/bjoc.5.57
Scheme 1: Synthesis of tetraphenylenes 2.
Figure 1: DSC traces of compound 2h during (a) second cooling and (b) second heating (heating/cooling rate 5 ...
Figure 2: Texture of 2h under the POM at 25 °C upon cooling from the isotropic liquid (heating/cooling rate 5...
Figure 3: Molecular modelling of the saddle-shaped tetraphenylene (octakis)acyl core unit of 2 [35].
Figure 4: Clearing temperatures Tcl [°C] of tetraphenylenes 2e–l as a function of the chain lengths n.
Figure 5: The differences between the clearing temperatures Tcl [°C] of tetraphenylenes 2 and the melting poi...